Mitigating Pt Loss in Polymer Electrolyte Membrane Fuel Cell Cathode Catalysts Using Graphene Nanoplatelet Pickering Emulsion Processing

نویسندگان

چکیده

Carbon-supported Pt nanoparticles are the leading catalysts for cathode oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cells. However, these ORR suffer from poor electrochemical durability, particularly loss of surface area (ECSA) due to nanoparticle dissolution and agglomeration. Here, is mitigated through a Pickering emulsion-processing strategy that employs graphene nanoplatelet dispersions stabilized by ethyl cellulose. The resulting graphene-Pt/Vulcan carbon (Pt/C) exhibit superior durability ECSA retention throughout an accelerated stress test compared with commercial Pt/C standard catalyst, both diagnostic-rotating disc electrode setup assembly full cell. These graphene-Pt/C also improve at high-voltage conditions, providing further evidence their exceptional stability. Consistent density functional theory calculations, postelectrochemical characterization reveals localize defects on basal plane especially edges nanoplatelets. Since this localization suppresses agglomeration without hindering accessibility reactant species catalyst surface, performance under idealized practical experimental conditions shows significantly improved while maintaining high activity.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2022

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202205216